I'm actually using Netlimiter at the moment and i seem to have tracked the problem down to SQL traffic. Further investigation has found a DTS package that uploads a 200MB database to our network every few minutes!!
I've actaully used Netlimiter to restrict this traffic and am currently in talks with those responsible as to why so much traffic must be uploaded so frequently
You're recommendations have been taken onboard though, and i will investigate them in time, there's obviously a need for us to be running this kind of analysis on an ongoing basis...
Thanks again
Dan.